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This article is mainly about the principle of TEMPO free radical(2,2,6,6-tetramethylpiperidine-1-oxyl, 2564-83-2) oxidation, why the reaction can be selective and how to reduce the consumption of TEMPO. Presented by NanJing Liskon Biological Technology Co.,ltd.
TEMPO oxidizes alcohols to aldehydes and ketonesIn 1987, Anelli reported the oxidation of alcohols to aldehydes and ketones using TEMPO (CA.1% mol), NaOCl, KBr and NaHCO3 in dichloromethane - water two-phase solvent.TEMPO also called 2,2,6,6-tetramethylpiperidine-1-oxide, or 2,2,6,6-tetramethylpiper
QUESTION:TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl, or (2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl),Given that it's a free radical, why doesn't it react with itself, despite being capable of reacting with other radicals in the system itself)?In addition, according to Wikipedia, it's a red-orang
Oxidizers and catalysts are widely used in medicines and pesticides production. 2,2,6,6-tetramethylpiperidinyloxy(CAS:2564-83-2), commonly known as TEMPO, can be used both ways, and it has excellent stability in storage condition.Following is chemical properties of TEMPO:Appearance: red crystalMolec
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